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Solvothermal techniques allow the crystallization of high nuclearity products that are otherwise inaccessible by conventional techniques, directly from the reaction mixture. By this method, the reaction of the triangular species [Fe3O(OAc)6(H2O)3]Cl with benzotriazole (BtaH) produces an [Fe14] cluster (depicted) with a very large spin ground state.
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Low et al. (2003) studied this question.
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