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The general concepts, advantages, and applications of pentaquadrupole mass spectrometry and of a variety of pentaquadrupole multidimensional triple-stage (MS3) scans as applied to the study of gas-phase ion/molecule reactions are reviewed. An overview is presented of the development and the present stage of triple-stage pentaquadrupole mass spectrometry, and examples of successful applications of “QqQqQ-MS” in revealing, elucidating, and helping to consolidate new classes of gas-phase ion/molecule reactions are summarized. The variety of features and advantages that make pentaquadrupoles most suitable laboratories for studies of ion/molecule reactions, and the exceptional gains in chemical information and selectivity of QqQqQ-MS are also discussed.
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Marcos N. Eberlin (1997) studied this question.
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