Ionic radius-dependent self-assembly of lanthanide organic polyhedra: structural diversities and luminescent properties

Jing Su; Fan Yin; Xiao‐Fang Duan; Jingyao Zhou; Li‐Peng Zhou; Chong‐Bin Tian; Qing‐Fu Sun

doi:10.1039/d5qi00265f

January 1, 2025Inorganic Chemistry Frontiers

Ionic radius-dependent self-assembly of lanthanide organic polyhedra: structural diversities and luminescent properties

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Key Points

To investigate how lanthanide ionic radius and ligand conformational flexibility influence the self-assembly, structural diversity, and luminescent behaviors of lanthanide organic polyhedra.
Synthesized lanthanide coordination cages using lanthanide metal ions of varying ionic radii paired with conformationally flexible ligands.
Characterized the resulting molecular polyhedra architectures and evaluated their corresponding photophysical and luminescent profiles.
Variations in lanthanide ionic radius directly altered the self-assembly pathways, yielding distinct polyhedral architectures.
Ligand conformational flexibility acted cooperatively with lanthanide size to modulate the emission efficiency and luminescent characteristics of the complexes.

Implication

Structural study reveals ionic radius governs lanthanide polyhedral assembly, highlighting methods to tune luminescence.

Abstract

This article presents the influence of lanthanide size and ligands conformational flexibility on the lanthanide assemblies and their corresponding luminescent properties.

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Cite This Study

Su et al. (2025) studied this question.

synapsesocial.com/papers/6a7cc52bf1688b70c061196a https://doi.org/10.1039/d5qi00265f

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Ionic radius-dependent self-assembly of lanthanide organic polyhedra: structural diversities and luminescent properties

Key Points

Implication

Abstract

Discussion

Cite This Study

Ionic radius-dependent self-assembly of lanthanide organic polyhedra: structural diversities and luminescent properties

Key Points

Implication

Abstract

Discussion

Cite This Study

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