-rich atmosphere is significant at least for pressures from 1.0 bar and that plasma-dust interaction is insignificant. The formation of sulfur and polysulfides indicates fractionation and possible loss of volatile elements caused by the heat of the LIBS laser. This should be taken into account when interpreting combined LIBS-Raman analyses of minerals containing volatile elements on planetary surfaces.
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Alsemgeest et al. (2022) studied this question.
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