Relationships among dissolved organic matter, iron, and discharge in a moorland stream

Dissolved organic matter (DOM) and iron in a moorland stream were determined at 8‐hour intervals over a 6‐month period to examine relationships with streamflow. Regression of both solutes on discharge were positive and explained 50–70 per cent of the variance in the solute data, but better predictions were obtained in both cases when a covariate reflecting temporal variation in the relationships was introduced (explained variance 80–90 per cent). Variations in the regression of Fe on DOM were also identified, indicating differences in the complexing power of DOM for Fe and possible variations in the chemical composition of the DOM.