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Reaction of [tBu3PN2O(B(C6H4F)3)] with 1, 1.5, or 2 equivalents of Zn(C6F5)2 affords the species [{tBu3PN2OZn(C6F5)2}2], [{tBu3PN2OZn(C6F5)2}2Zn(C6F5)2], and [tBu3PN2O{Zn(C6F5)2}2] displaying unique binding modes of Zn to the phosphine-stabilized N2O fragment. Original language English Pages (from-to) 9709-9712 Number of pages 4 Journal Angewandte Chemie International Edition Volume 48 Issue number 51 DOIs https://doi.org/10.1002/ange.200905650 Publication status Published - 2009 Keywords zinc nitrous oxide frustrated Lewis pairs
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Neu et al. (2009) studied this question.
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