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Neutron and X-ray structures reveal oxidation insights in O2-sensitive hydrogenase, suggesting roles of thiolate ligands.
with a distance of 3.25 Å, where the amide proton appears to be delocalized between the donor and acceptor atoms. This observation provides insight into the contribution of the coordinated thiolate ligands to the redox reaction of the Fe-S cluster.
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Hiromoto et al. (2023) studied this question.
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