A simple, efficient and eco‐friendly method for the vicinal dihalogenation of alkenes is described. The reaction is performed with a combination of a N ‐halosuccinimide and an alkali metal halide using environmentally benign solvents such as acetic acid and ethyl acetate. Purification steps are avoided, and pure products are usually obtained after a simple aqueous workup.
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Rubio‐Presa et al. (2021) studied this question.
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