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This review aims to summarize the current advancements in radical-initiated trifluoroacetylation techniques.

Recent Advances in Radical‐Initiated Trifluoroacetylations

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This review aims to summarize the current advancements in radical-initiated trifluoroacetylation techniques.
Systematic classification of trifluoroacetyl precursors and their transformations.
Analysis of mechanistic pathways and reaction conditions.
Discussion of substrate scopes and synthetic applications.
Comprehensive overview of four types of trifluoroacetyl precursors is provided.
General superiority of each trifluoroacetylation protocol is highlighted.
Current challenges and future directions for trifluoroacetylation methods are addressed.

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Review summarizes radical-mediated trifluoroacetylation outcomes in organic molecules, suggesting new efficient methods.

Jiang et al. (2026) studied this question.

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