The results of detailed measurements of osmotic pressure, light scattering, and viscosity of poly(vinyl chloride) solutions are used to establish the molecular weight dependence of [η] and A 2 , to estimate the unperturbed dimensions of the poly(vinyl chloride) molecule, and to analyze critically the [η]– M correlations published hitherto.
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Bohdanecký et al. (1967) studied this question.