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The interactions of luminescent platinum metal complexes with a variety of organized media, including micelles, cyclodextrins, and solid polymers, are described. In particular, Ru(II), Os(II), and Re(I) complexes with α-diimine ligands are discussed. Applications of these systems, including luminescence quantum counters, singlet oxygen generators, and a luminescent oxygen sensor, are described. Useful tools for studying these systems are described; these include a deuterium isotope method for measuring the degree of solvent exposure of bound sensitizers, excited-state-lifetime titrations for examining the compositions of systems, and spectral fitting and temperature profiles for probing excited state ordering and energies.
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Demas et al. (1988) studied this question.
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