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All articles of this category The development of our research concerning the substituent and solvent effects in intramolecular Diels-Alder reactions is presented. From this work we have determined the importance of relative factors in accelerating cyclizations due to the gem -dialkyl effect, established the enthalpic basis for this acceleration, and observed an important, heretofore unrecognized, solvent effect on intramolecular Diels-Alder reactions in which the diene and dienophile are attached by an ester linkage. 1. Introduction 2. The Basis for the gem -Dialkyl Effect: The Reactive-Rotamer Effect or the Thorpe-lngold Effect? 3. Solvent Effects in the Intramolecular Diels-Alder Reaction of Substrates Having an Ester Linkage 4. Conclusion
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Michael E. Jung (1990) studied this question.
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