Secondary kinetic isotope effects involving deuterated nucleophiles

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Synapse has enriched 4 closely related papers on similar clinical questions. Consider them for comparative context:

1. 1Isotope effects in nucleophilic substitution reactions. IV. The effect of changing a substituent at the α carbon on the structure of S N 2 transition states1982 · 38 citations
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3. 3.alpha.-Deuterium isotope effects in benzyl halides. 2. Reaction of nucleophiles with substituted benzyl bromides. Evidence for a change in transition-state structure with electron-donating substituents1980 · 35 citations
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