POM and luminescence: The first charge transfer intercluster crystal has been synthesized by using [Ag62S13(StBu)32]4+ as the cation and Mo6O192− as the anion. Its luminescence behavior is controlled by the electron accepting ability of the polyoxometalate (POM). The emission quenched by the charge transfer could be turned on by allowing the sample to contact halohydrocarbons (see figure).
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Xiao et al. (2012) studied this question.
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