Supramolecular intercluster compounds, that is, assemblies of different, well‐defined inorganic building blocks with diameters of >1 nm, consisting of [Au 9 (PPh 3 ) 8 ] 3+ clusters and Keggin anions [PW 12 O 40 ] 3– were synthesized as single‐crystals by a diffusion method. Depending on the solvent combination, two modifications with different core geometries of the gold cluster and different overall packing type can be obtained as a single‐phase in macroscopic amounts. This approach leads toward the study of nanostructured matter with high translational symmetry and the principles of nanoscopic self‐assembly. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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Schulz‐Dobrick et al. (2006) studied this question.
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