The double salts AgSCN·2AgNO3 and AgSCN·AgClO4 both feature an unprecedented µ5-1,2,3κS:4,5κN coordination mode of the thiocyanate ligand, which generates a two- or three-dimensional network according to the relative coordinating capability of the co-existing nitrate or perchlorate anion.
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Guo et al. (1999) studied this question.
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