Oxidation of phenols by the excited state of an osmium( vi ) nitrido complex

Lixin Wang; Rui-Yue Qi; Jing Xiang; Tai‐Chu Lau

doi:10.1039/d4qi03144j

January 1, 2025Inorganic Chemistry FrontiersOpen Access

Oxidation of phenols by the excited state of an osmium( vi ) nitrido complex

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Key Points

To investigate the photochemical oxidation of diverse phenol substrates mediated by the excited state of an osmium(VI) nitrido complex.
Examined the photoreactivity of the anionic osmium(VI) nitrido complex, [OsVI(N)(L)(CN)3]−, in the presence of various substituted phenols under photoexcitation.
Demonstrated photo-induced oxidative reactivity of the excited-state osmium(VI) nitrido complex toward phenol derivatives.
Identified product formation and substrate transformation across multiple phenol derivatives under light-driven conditions.

Implication

Photochemical study demonstrates oxidation of various phenols by an excited-state osmium(VI) nitrido complex, highlighting new pathways for transition-metal photo-redox reactions.

Abstract

The photoreaction of an osmium(VI) nitrido complex, [OsVI(N)(L)(CN)3]‒ (OsN), with various phenols has been investigated. Upon irradiation of OsN with visible light, the excited state (OsN*) is generated which reacts...

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Cite This Study

Wang et al. (2025) studied this question.

synapsesocial.com/papers/6a7f5197aa5aedc584ad02ef https://doi.org/10.1039/d4qi03144j

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Oxidation of phenols by the excited state of an osmium( vi ) nitrido complex

Key Points

Implication

Abstract

Discussion

Cite This Study

Oxidation of phenols by the excited state of an osmium( vi ) nitrido complex

Key Points

Implication

Abstract

Discussion

Cite This Study

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