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The reaction of aryloxazolines with trialkylhydrosilanes using Ru3(CO)12 or Ru(H)2(CO)(PPh3)3 complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yields. This reaction can be applied to aryloxazolines having either electron-donating (Nme2, Ome, and CH3) or -withdrawing (CF3 and F) groups.
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Kakiuchi et al. (2001) studied this question.
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