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New phosphoramidites were applied as chiral ligands in the Cu‐catalyzed allylic alkylation with dialkylzinc reagents. A variety of substrates, reagents and chiral ligands were screened, resulting in improved catalytic methodology for allylic bromides in which enantioselectivities up to 88% were reached.
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Zijl et al. (2004) studied this question.
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