Characterization of Asphaltenes and Resins From Problematic Mexican Crude Oils

Asphaltenes and resins have been separated from four mexican oils suffering from the deposition of asphaltenic material during recovery operations. A SARA separation of the oils was performed and the resins and asphaltenes further analyzed. Characterization methods employed were FTIR, elemental composition both of CHNSO, and trace metals and molecular weight determination using size exclusion chromatography. NMR techniques were applied to two asphaltene samples. The overall scope of the work was to get a better understanding of the nature of the asphaltene stability at a molecular level in these problematic oils. Separation of resin in two fractions indicates that there is no long alkyl chains in these as given by FTIR, which may be the cause of the lack of stability along with the large difference in bubble point and reservoir pressure.