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High-temperature diffusion of boron or phosphorus into silicon leads to the formation of spherical precipitates and/or dislocation loops in the diffused layer which influence electrical junction characteristics. These diffusion-induced imperfections can be removed by high-energy pulse laser treatment. The boron or phosphorus atoms previously contained in the precipitates become electrically active and the resulting dopant concentration can exceed the solid solubility limit.
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Young et al. (1978) studied this question.
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