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Electrochemical properties of graphite were investigated using -based glass or -based glass as a solid electrolyte. Graphite showed reversible electrode reactions in the -based glass, while it did not in the -based one. The results of X-ray diffractometry and Raman spectroscopy indicated that the -based glass was reduced as side reactions instead of the intercalation of lithium ions into graphite during the reduction, resulting in the poor reversibility.
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Takada et al. (2003) studied this question.
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