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1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane ( I ) reacts with cytosine arabinoside ( II ) in pyridine under the formation of 3',5'-O-(tetraisopropyldisiloxane-1,3-diyl)cytosine arabinoside ( IIIa ) and with 1-(6'-deoxy-α-L-talofuranosyl)uracil ( V ) under the formation of 2',3'-O-(tetraisopropyldisiloxane-1,3-diyl) 1-(6-deoxy-α-L-talofuranosyl)uracil ( VIa ).
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Markiewicz et al. (1980) studied this question.
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