Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra

Summary Conditions necessary for exchange between lattice OH groups and D 2 O in expanding layer silicates are reported. From spectral changes in the 200–1200 cm −1 region resulting from this exchange, in-plane librations of OH co-ordinated to (A1A1), (A1Mg), (A1Fe 3+ ), and (MgMgMg) have been identified in montmorillonite, beidellite, saponite, hectorite, and vermiculite. Both in-plane and out-of-plane librations have been identified for pyrophyllite and celadonite, from comparison of synthetic specimens containing OD with natural or synthetic OH forms. Comparison of hydrogen and deuterium forms of Mg- and Ni-talcs leads to the identification of translational and librational OH vibrations.