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Redox “B”ees: Rational design of a new series of boron-functionalized NiIII/NiIV–bis(dicarbollide) clusters results in a family of robust and tunable redox shuttles (see diagram; EDG and EWG denote electron-donating and -withdrawing groups, respectively). This offers a means to rationally control the redox properties in dye-sensitized solar cells (DSCs), leading to exceptionally high open-circuit voltages.
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Spokoyny et al. (2010) studied this question.
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