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The total syntheses of (+)-asperlin 1, (+)-acetylphomalactone 2 and (5S,6S,7R,8S)-asperlin 3 have been achieved employing the kinetic resolution of unsymmetric divinylmethanol using modified Sharpless reagents, which produced two oxidation products, as a key step.
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Yang et al. (1997) studied this question.
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