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First time-resolved photoemission experiments employing attosecond streaking of electrons emitted by an extended ultraviolet pump pulse and probed by a few-cycle near-infrared pulse found a time delay of about 100 as between photoelectrons from the conduction band and those from the $4f$ core level of tungsten. We present a microscopic simulation of the emission time and energy spectra employing a classical transport theory. Emission spectra and streaking images are well reproduced. Different contributions to the delayed emission of core electrons are identified: larger emission depth, slowing down by inelastic-scattering processes, and possibly, energy-dependent deviations from the free-electron dispersion. We find delay times near the lower bound of the experimental data.
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Lemell et al. (2009) studied this question.
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