Powerful reactions such as Wittig olefinations, nitro-aldol additions, dipolar cycloadditions, and Heck coupling reactions can be mediated by DNA templates. The yields of several DNA-templated reaction products are independent of the number of bases (n=0 or 10) separating the annealed reactive groups (as an example, the denaturing polyacrylamide gel electrophoresis of a DNA-templated Wittig reaction is shown).
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Gartner et al. (2002) studied this question.
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