We found a new method for the preparation of gold nanorod and nanosphere films. The nanoparticle films could be formed at the liquid-liquid interface between aqueous and hexane solutions and were almost monolayers. Surface-enhanced Raman scattering (SERS) spectra of rhodamine 6G under the nonresonance condition were measured using these films as SERS substrates. It is experimentally demonstrated that nanorods with a higher aspect ratio are more effective in SERS enhancement.
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Suzuki et al. (2004) studied this question.
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