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All articles of this category A direct way to prepare cis,exo -hexahydromethano- or -ethanobiphenylene derivatives involving intramolecular aromatic C-H activation is reported. It consists of the palladium-catalyzed reaction of a rigid olefin with an aryl halide in dimethyl formamide in the presence of potassium carbonate. biphenylene derivatives - strained rings - aromatic C-H activation - palladium - catalysis
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Catellani et al. (1996) studied this question.
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