Reaction of an aqueous solution of Na2bpdc (H2bpdc = biphenyldicarboxylic acid) with an organic solution of Co(NO3)2via a diffusion route leads to a pillared three-dimensional structure in which the heterometallic sodium(I)–cobalt(II) trilayers are connected by carboxylate groups of the pillared ligand bpdc2−.
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Pan et al. (2001) studied this question.
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