The Fe Kα x-ray spectrum produced by 30-MeV O⁵⁺ bombardment is found to consist of two major components which have been identified as 1s→2p transitions shifted 38 and 68 eV above the Kα1,2 energy due primarily to one and two additional vacancies, respectively, in the $2p$ shell.
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Burch et al. (1971) studied this question.
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