Fluorine has been introduced into the LOCOS field oxide by high-energy (2-MeV) F implantation and subsequent annealing at 950 degrees C for 60 min. Improved radiation hardness of the field oxide and its associated device parameters was observed. N-channel MOSFETs isolated by the fluorinated oxide exhibit a lower radiation-induced source-drain leakage current. This is attributed to the smaller density of radiation-induced positive oxide charge in the fluorinated field oxide compared to its control. This is consistent with experimental results showing that threshold voltage shifts of the field-oxide FETs are smaller than their control. In addition, the radiation-induced leakage currents of reverse biased n/sup +/p-junction diodes fabricated with the F implantation process are suppressed, suggesting that the generation of interface traps at the gate SiO/sub 2/-Si and the field SiO/sub 2/-Si interfaces is also reduced in the fluorinated devices.>
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Nishioka et al. (1990) studied this question.
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