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Intense stimulated emission from sodium vapor is observed at around 800 nm when it is pumped by a pulsed dye laser around 600 nm. The spectral lines are localized around 800 nm. To investigate the origin of this emission, we try to assign the stimulated lines excited by a dye laser at 632.8 nm (the wavelength of the He-Ne laser) and by a ruby laser at 694.3 nm. Moreover, the A Σ -X Σ transitions at 595.728 and 594.664 nm of a Na 2 which are newly assigned by using the polarization labelling spectroscopy are excited by the output from a cw-dye-laser amplified with N 2 laser-pumped dye amplifier, and some of the stimulated lines are assigned. It is then concluded that the origin of these stimulated emission lines is the A Σ -X Σ transition. Also it can be explained that these stimulated lines come from around the band edge of the A Σ -X Σ transition.
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Itoh et al. (1983) studied this question.
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