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Model calculations of the potential surfaces of van der Waals ions, consisting of a benzene cation bound to a rare-gas (R) atom, provide information concerning the reduction of the ionization potentials of benzene in the benzene–R1 complex, relative to that of the bare molecule, and establish the configuration changes accompanying the ionization of benzene–R1 complexes.
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Jortner et al. (1983) studied this question.
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