The thermal dehydrochlorination of PVC has been examined on some samples prepared by fractionation of a commercial PVC, and some other samples obtained by polymerization at different temperatures. The results disagree with the concept of a continuous dehydrochlorination from one side to the other of the chain, that necessitates initiating structural anomalies in the macromolecule itself.
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Crosato‐Arnaldi et al. (1964) studied this question.
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