Self-assembly of new tetranuclear (1) and octanuclear (2) manganese carboxylate clusters is controlled by the bis(bipyridine) ligands L1 and L2, respectively, which are shown on the right. The cation 1 consists of two Mn2O complex fragments, each of which contains one MnII and one MnIII center; 2 contains two butterfly-like Mn4O2 cores linked by bis(bipyridine) bridges. Counterion: ClO.
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Knapp et al. (1996) studied this question.
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