Experimental study demonstrates one-step block copolymer synthesis via simultaneous ring-opening and radical polymerizations, highlighting an efficient route to complex macromolecular architectures.
Just one step is required for the synthesis of block copolymers by simultaneous "living"/controlled ring-opening and radical polymerization initiated by a difunctional (A-B) compound (shown schematically on the right).
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Mecerreyes et al. (1998) studied this question.
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