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A simple and efficient methodology has been established for the selective synthesis of anatase and rutile as well as their mixtures with various precursors using ultrasound irradiation; the products, the particle sizes of which are nanometric (<9 nm), are dependent both upon the reaction temperature and the precursor used; a substantial reduction in reaction time as well as reaction temperature is observed as compared to the corresponding hydrothemal processes.
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Huang et al. (2000) studied this question.
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