In this work, we report the temperature-dependent field emission properties of 3 C -SiC nanoneedles (SiCNNs) in the range of room temperature (RT) to 500 °C. SiCNNs are synthesized via catalyst-assisted pyrolysis of a polyaluminasilazane precursor. The obtained SiC nanostructures are needlelike shaped with numerous sharp corners around the tiny tips. Field emission characteristics show that turn-on field ( E to ) of as-synthesized SiCNNs are ranged in 1.30 to 0.66 V/μm with the temperature raised from RT to 500 °C. At a fixed electric field of 1.37 V/μm, about a three-order-of-magnitude increase of the emission current level has been observed. We attribute the significant reduction of E to and the remarkable increase of emission current to the decrease of work function induced by the raise of temperatures.
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Wei et al. (2011) studied this question.
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