The canonical method of Andersen and Jepsen for determining the band structure of metals, which is based on the linear muffin-tin orbital method and which leads to an extremely simple tight-binding method, is generalized to the case of random alloys. The factorization of the structural- and potential-dependent parts allows one to perform the configurational averaging within the single-site approximation. The theory is illustrated for the Agₓ{Pd}_{100{{-}}x}$ alloy series.
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Kudrnovský et al. (1987) studied this question.
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