Stereospecific Synthesis of Highly Substituted Skipped Dienes through Multifunctional Palladium Catalysis

This is the authors' abstract. We don't add key points for this paper.

[reaction: see text] Multifunctional palladium catalysis is utilized in the one-pot stereocontrolled synthesis of tetrasubstituted alkenes. The homogeneous palladium dihalide catalyst utilized for bromo-/chloroallylation of alkynes is then reused in situ for a subsequent Suzuki cross-coupling reaction.