Fillings and cavities: Three novel pseudo-octahedral metal–organic frameworks, 1–3, consisting of macrometallacyclic noninterpenetrating meso networks and exhibiting weak antiferromagnetic interactions, have been constructed from CuII centers and structurally flexible R,S-bis(sulfinyl) ligands. Varying the chain length of ligands is found to control the cavity sizes of the networks.
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Bu et al. (2001) studied this question.
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