Answers are grounded in this paper and cite their sources.
A study of photo‐induced electron‐transfer reactions in MeCN with 9,10‐dicyanoanthracene as acceptor and 21 electron donors with transient photoconductivity measurements is reported. The free‐ion yield and the rate constant of back electron transfer are determined. For exergonic reactions, the ‘ Marcus ‐inverted’ region is observed. The fit with the theory is best, when a nearly solvent‐independent Coulomb term is used in the calculation of the energy balance.
No takes yet. Share an insight, caveat, or question.
Vauthey et al. (1988) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: