Addition reactions of ethynyltrimethylsilane to various quinolines and isoquinolines activated by acyl chloride are catalyzed with a few Ir-complexes to afford 2-trimethylsilylethynyl-1,2-dihydroquinolines and 1-trimethylsilylethynyl-1,2-dihydroisoquinolines in good to high yields.
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Yamazaki et al. (2004) studied this question.
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