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Fast atom bombardment, a new method of ionizing molecules for mass spectrometry, has been found to be particularly applicable to molecules of an involatile nature. The mass spectra of vitamin B12 and related cobalamines are reported together with the mass spectrum of the coenzyme of vitamin B12. Fully resolved spectra, containing both molecular species and structurally significant fragmentation are reported for the first time.
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Barber et al. (1981) studied this question.
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