Giant rod–coil amphiphilic block copolymers were prepared by metallocene-catalyzed polymerization. The hydrophilic coiled block consists of polymethacrylic acid and the rod component of a hydrophobic cylindrical brush polymer. The high solubility of the stiff block results in the micelles being formed with the stiff block forming the solubilizing corona.
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Neiser et al. (2004) studied this question.
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