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A new type of copolymer was synthesized by ring-opening polymerization of 1,3-dioxan-2-one (TMC) and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane (TMP) using (i-C4H9)3Al as the initiator. The chemical structure was characterized by 1H nuclear magnetic resonance and Fourier transform infrared. The respective reactivity ratios of TMC and TMP were determined using the Kelen–Tüdös method. Conversion studies showed that the composition of the copolymer agree with the feed composition at high conversions.
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Hu et al. (1998) studied this question.
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