Hydrolysis of the complex [1,3-C6H4(OPPh2AuSPh)2] gives the emissive, neutral tetragold(I) complex [{Au2(μ-SPh)(PPh2O)(PPh2OH)}2], which is associated through pairs of gold···gold interactions and P−O−H···O−P hydrogen bonds.
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Hunks et al. (2000) studied this question.
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