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Mild conditions have been developed to achieve a Pd(OAc)(2)-catalyzed cross-coupling between indoles and arylsiloxanes in the presence of TBAF and Ag(2)O in acidic medium. Electron-deficient arylsiloxanes presented high efficiency in this system to give the arylated indoles in excellent yields.
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Liang et al. (2010) studied this question.
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